Non‐Fermi Liquids as Highly Active Oxygen Evolution Reaction Catalysts

نویسندگان

  • Shigeto Hirai
  • Shunsuke Yagi
  • Wei‐Tin Chen
  • Fang‐Cheng Chou
  • Noriyasu Okazaki
  • Tomoya Ohno
  • Hisao Suzuki
  • Takeshi Matsuda
چکیده

The oxygen evolution reaction (OER) plays a key role in emerging energy conversion technologies such as rechargeable metal-air batteries, and direct solar water splitting. Herein, a remarkably low overpotential of ≈150 mV at 10 mA cm-2disk in alkaline solutions using one of the non-Fermi liquids, Hg2Ru2O7, is reported. Hg2Ru2O7 displays a rapid increase in current density and excellent durability as an OER catalyst. This outstanding catalytic performance is realized through the coexistence of localized d-bands with the metallic state that is unique to non-Fermi liquids. The findings indicate that non-Fermi liquids could greatly improve the design of highly active OER catalysts.

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عنوان ژورنال:

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2017